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Meeting 2021 TMS Annual Meeting & Exhibition
Symposium High Temperature Electrochemistry IV
Presentation Title Investigation on Preparation of Fe-Al Alloys by Direct Reduction of Fe2O3-Al2O3 Powder in CaCl2-NaCl Molten Salt System
Author(s) Jinrui Liu, Hui Li, Jinglong Liang
On-Site Speaker (Planned) Hui Li
Abstract Scope Fe-Al Alloys has been synthesized directly from Fe2O3-Al2O3 powder by electro-deoxidation in the CaCl2-NaCl molten salt at 800 °C. The thermodynamic decomposition voltages of Fe2O3, Al2O3 and compounds in molten salt to their corresponding metal in 800 °C has been analyzed. Constant voltage electrolysis has been utilized to investigate the formation process of Fe-Al Alloys. The results indicated that Fe2O3 is decomposed into Fe earlier. It is found that with the first reduction product Fe, the later reduction product Al will immediately form Fe3Al and FeAl which are more refractory, avoiding the loss of Al due to its low melting point thereby.
Proceedings Inclusion? Planned:

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Comparative Study of Working Electrode Materials for Voltammetry Measurements in LiCl–Li2O Salts
Advances in Solid Oxide Membrane Based Electrolysis for Solar-grade Silicon Deposition
Effect of Hydroxide and Oxide Impurities in Electrochemical Processes Using Molten LiCl and CaCl2
Electrochemical Reactions of Oxide Ions with Tungsten in Molten CaCl2
Feasibility of Potentiometry for Monitoring Activity of GdCl3 in Molten LiCl-KCl Salt
First-principles Molecular Dynamics and CALPHAD Modeling of the CaF2-MgF2-SiO2 Molten Salt System
Fundamental Challenges for the Development of Electrolytic Reduction of Uranium Oxide in Molten LiCl-Li2O
High-speed Electrodeposition of Textured Monolithic Lithiated Transition Metal Oxide Cathodes for Low Cost, High Energy, and Fast Charging Li-ion Batteries.
Interaction between Solute Species and Metallic Alloying Elements in Molten Chloride Systems
Investigation on Preparation of Fe-Al Alloys by Direct Reduction of Fe2O3-Al2O3 Powder in CaCl2-NaCl Molten Salt System
Liquid Bipolar Electrode for Extraction of Aluminium and PGM Concentrate from Spent Catalysts
Molten Hydroxide Mediated Electrosynthesis of Layered Transition Metal Oxides for Electrochemical Energy Storage
New Electrochemical Deoxidation Method of Ti Metal in Molten Salts Containing YCl3
Optimizing Reaction Selectivity in High Temperature Molten Electrolytes
Selective Extraction of Gold from Gold-copper Alloy Using Anodic Electrochemical Deposition in Molten Salt Electrolyte
Validated Modeling of Quartzite Reduction to Solar Silicon by Molten Salt Electrolysis

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