| About this Abstract |
| Meeting |
2025 TMS Annual Meeting & Exhibition
|
| Symposium
|
Spectroscopic Methods and Analysis for Nuclear Energy Related Materials
|
| Presentation Title |
Atomic-scale structural analysis of metastable zirconia |
| Author(s) |
Maik K. Lang, Alexandre Solomon, Eric O'Quinn, Gianguido Baldinozzi, Juejing Liu, Xiaofeng Guo, Joerg Neuefeind, Christina Trautmann, Rodney C. Ewing |
| On-Site Speaker (Planned) |
Maik K. Lang |
| Abstract Scope |
Solid-state Phases that exist beyond their thermodynamic fields of stability are important to emerging technologies. Metastable phases are prevalent in far-from-equilibrium processing approaches and often exhibit desirable chemical and physical properties. However, there is limited understanding of the atomic-scale structural mechanisms that allow metastable phases to be recovered to ambient conditions. Metastability plays an important role in the synthesis of different zirconia (ZrO2) polymorphs. We utilized a complementary approach of neutron total scattering and Extended X-ray Absorption Fine-Structure (EXAFS) analysis to investigate the atomic-scale recovery process and structural properties of the metastable tetragonal phase. Grain-size reduction to the nanometer range and bombardment with high-energy (GeV) ions were used to prepare this metastable form of zirconia. We show in this presentation that the formation of a hierarchical network of nanoscale domains of lower symmetry, separated by domain walls, is the underlying structural mechanism that provides the pathway to the metastable state. |
| Proceedings Inclusion? |
Planned: |