About this Abstract |
Meeting |
2025 TMS Annual Meeting & Exhibition
|
Symposium
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Environmental Degradation of Multiple Principal Component Materials
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Presentation Title |
Alumina-Forming Nb-Mo-Ti-Al Bond Coat Alloys |
Author(s) |
Melina A. Endsley, Collin S. Holgate, Chiyo McMullin, Michael Worku, Carlos G. Levi, Tresa M. Pollock |
On-Site Speaker (Planned) |
Melina A. Endsley |
Abstract Scope |
Refractory multi-principal element alloys (RMPEAs) are promising candidates for replacing Ni-based superalloys in high temperature gas turbine engines due to their high melting temperatures. However, these alloys generally exhibit poor oxidation resistance, and will therefore require oxidation-resistant bond coatings, which historically have provided protection via formation of a dense alumina scale. Unfortunately, current alumina-forming bond coat alloys have inadequate temperature capabilities and are thermochemically incompatible with state-of-the-art RMPEAs, motivating the design of new protective bond coatings. Thermodynamic modeling (CALPHAD) and machine learning-based clustering were used to select promising alloys in the Nb-Mo-Ti-Al composition space. Alloys were then synthesized via arc melting for evaluation. Alloys that oxidized favorably to form a continuous and adherent alumina scale at 1400°C under isothermal conditions will be presented. Cyclic and kinetic oxidation studies and microstructural evolution across a range of temperature will also be discussed. |
Proceedings Inclusion? |
Planned: |
Keywords |
Surface Modification and Coatings, High-Temperature Materials, Other |