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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium Advances in Surface Engineering VII
Presentation Title Pattern Formation via the Oriented Growth of Au-Si Thin Films on Si(001) Substrate
Author(s) Rotem Zilberberg, Iryna Polishchuk, Lotan Portal, Silvia Milita, Giuseppe Falini, Alexander Katsman, Boaz Pokroy
On-Site Speaker (Planned) Rotem Zilberberg
Abstract Scope The fabrication of patterned surfaces is integral to various device manufacturing processes and requires precise manipulation of surface properties. This study (Zilberberg et al., Acta Mater, 2024) introduces a self-driven approach for patterning metal and semiconductor surfaces by solidifying eutectic Au-Si thin films on Si(001) substrates. The resulting pattern encompasses meticulously aligned Au-Si eutectic structures and Si islands attributed to the epitaxial growth of Si(001), Au(001), and Au(011) within the films. This was corroborated through electron diffraction and synchrotron radiation grazing-incidence wide-angle X-ray scattering (GIWAXS). We propose a 4:3 coincident site lattice model to elucidate the Au-Si interface, explaining the dominant (001)[110]Au||(001)[110]Si orientation relationship that minimizes the lattice mismatch to 0.2%. Another observed orientation relationship, (110)[001]Au||(001)[110]Si, entails a 6.3% mismatch in one direction, leading to contrasting elastic strains in the Au and Si lattices. This study underscores the practicality of substrate-oriented pattern formation, with potential applications in other phase-separated systems.
Proceedings Inclusion? Planned:
Keywords Surface Modification and Coatings, Solidification, Thin Films and Interfaces

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Application of Self-Supporting Vermiculite Membrane in LiCl/MgCl2 Separation
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Cold spray and peening surface treatment technologies for mitigating corrosion and SCC in stainless steel containments for used nuclear fuel storage
Controlling the spangle size and crystallographic texture of hot-dip galvanized coatings through substrate surface modification
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Diffusion-induced recrystallization associated with heterogeneous elemental distributions during carburization of Ni-Cr-Fe alloys
Effect of plasma spraying parameters on corrosion behavior of Fe- based amorphous/crystalline composite coatings
Effect of the Welding Current on the Liquid Metal Embrittlement of Galvanized TWIP950 Advanced High Strength Steel
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Graphene Nanocomposite Films on Carbon-Coated Metals: A Path to Macroscale Superlubricity
Harvesting dislocations and deformation twin traces for auto-catalytic growth of semiconductors on surfaces of gold alloys and gold thin-films
High-Temperature Surface Nitridation of 316H Stainless Steel: Formation of Nanolayered Nitride- Metal Composites
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Micro-textured Slippery Aluminium Alloys for Marine Applications
Microstructural Evolution and High Temperature Tribology of Wrought and Additively Manufactured Nickel-based Superalloy Subjected to Surface Enhancement Processes
Pattern Formation via the Oriented Growth of Au-Si Thin Films on Si(001) Substrate
Plasma spray of micro-Co-based coating on 55NiCrMoV7 steel
Preparation Techniques and Mechanical Properties of Ni-Co-B-SiC Coatings for Wear-Resistant Applications
Role of current density on the tribological and electrochemical properties of Zn-Co coatings deposited from a non-aqueous-based electrolyte.
Surface finishing of AM metallic parts by electrochemical polishing
Thin Films Contact Deformation by Gaussian and non-Gaussian Rough Surfaces: a Dislocation Dynamics Study
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