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Meeting MS&T24: Materials Science & Technology
Symposium Computation Assisted Materials Development for Improved Corrosion Resistance
Presentation Title Assessment of the Role of Minor Refractory Alloying Additions in Affecting Alumina-Scale Formation During High-Temperature Oxidation of Ni-based model alloys
Author(s) Rafael T. Rodriguez De Vecchis, Rishi Pillai, Kim Kisslinger, Meng Li, Judith Yang, Brian Gleeson
On-Site Speaker (Planned) Rafael T. Rodriguez De Vecchis
Abstract Scope During the last decades, new generations of Ni-based superalloys have emerged with judiciously controlled chemistries. These alloys heavily rely on the addition of refractory elements to enhance their mechanical properties at elevated temperatures, however, a clear interpretation of the influence of these minor-element additions on the alloy’s high-temperature oxidation is still not well understood, particularly from the standpoint of predicting the transition from internal to external alumina formation. In this context, the present investigation describes a systematic study that addresses the intrinsic effect that minor element additions of Nb, Ta, and Re have on the oxidation behavior of alumina-scale forming γ-Ni alloys. By combining a novel simulation approach with high-temperature oxidation experiments and advanced characterization techniques, the present study evidences the positive effect associated with 2 at. % addition of Ta and Re as well as the detrimental consequences of Nb additions on the 1100 °C oxidation of Ni-6Al-(0,4,6,8)Cr alloys.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Assessment of the Role of Minor Refractory Alloying Additions in Affecting Alumina-Scale Formation During High-Temperature Oxidation of Ni-based model alloys
Atomic Origins of CO2-Promoted Oxidation of Chromia-Forming Alloys
Impact of Water Vapor Content and Oxygen Partial Pressure on Oxidation Behavior of NiCr Alloys at 950 °C
New Approaches Towards Computational Modeling of Metal Dusting
Phase-Field Modeling of Thermally Grown Oxide and Induced Damage and Cracking in Environmental Barrier Coatings
Phase Field Numerical Model for Simulating the Activation and Diffusion Controlled Stress Corrosion Cracking Phenomena in Anisotropic Material
Predicting Oxidation Behavior of Ni-Based Superalloys with Physics-Informed Machine Learning
Quantifying the Impact of Microstructure on the Corrosion of Structural Alloys by Molten Salt Using Mesoscale Modeling with the MOOSE Framework
Re-Thinking Chemical Lifetime of Chromia-Forming Ferritic Stainless Steels

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