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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium Rare Metal Extraction & Processing
Presentation Title Preparation of High-Grade Sodium Tungstate from a Wolframite Ore for Catalytic Applications by Hydrometallurgical Process
Author(s) Alafara Abdullahi Baba, Sadisu GIRIGISU, Abdullah S. IBRAHIM, Fausat T. AKANJI, Folahan A. ADEKOLA
On-Site Speaker (Planned) Alafara Abdullahi Baba
Abstract Scope Wolframite ore, an industrial isomorphic mineral with varied Fe, Mn, and Pb ratios is useful in catalytic applications due to its astonishing properties including high melting points, hardness, excellent corrosion resistance, and thermal conductivity over other compounds. Consequently, the ore sourced from Anka, Zamfara State (Nigeria) was employed in studying the catalytic/oxidant properties using hydrometallurgical routes. The effects of process parameters such as reaction temperature, concentration, and particle size were investigated to obtain optimal extraction conditions for industrial tungsten compound. At optimal leaching (3M NaOH+0.15M H3PO4, 75°C, -90+75µm), 94.7% of the ore reacted within 120 minutes. The purification of the leachate by 0.25M Aliquat-336 yielded 96.7% pure tungsten, and was beneficiated to obtain high-grade Sodium Tungstate (Na2WO4.H2O : 96-901-3322, melting point: 703.4°C/698.1°C industrial standard). The product as characterized is recommended for use as a catalytic oxidant for defined industrial processes such as corrosion inhibitors in steel and high-tech applications.
Proceedings Inclusion? Planned:
Keywords Extraction and Processing, Hydrometallurgy, Characterization

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Challenges in Recycling of Rare Earth Elements Containing Permanent Magnets
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Efficient extraction of vanadium from calcification roasted high-calcium vanadium slag by sulfuric acid leaching
Extraction of Rare Earth Elements from Bastnasite Ore, and Separation of Heavy REEs and Light REEs by Solvent Extraction
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Green dissolution and separation of critical metal from nickel-metal hydride battery waste
Hydrometallurgical Extraction of Rhodium (III) from Chloride Media
Leaching Behavior of Hydrogen Peroxide in the Process of Recovering Silver from Spent Silver Catalysts
Microstructural observation on NdFeB magnets during pretreatments
Molten oxide electrolysis for production of technology-critical metals
Preparation of High-Grade Sodium Tungstate from a Wolframite Ore for Catalytic Applications by Hydrometallurgical Process
Recovery of Manganese Sulfate from Acidic Solutions Using Eutectic Freeze Crystallization
Recovery of Rhenium from Superalloy Swarf, Grindings, Turnings, and Scrap
Recycling of Strategic Metals from Spent Hydro-Desulphurization Catalysts Using Microbial Activities
Recycling Rare Earth Permanent Magnets via Liquid Magnesium Leaching and Distillation
Research Progress on Recovery of Platinum and Palladium from Spent Petrochemical Catalysts
Sustainable Hydrometallurgical Rare earth elements recovery from waste NdFeB magnet
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