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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium Environmental Degradation of Multiple Principal Component Materials
Presentation Title A High Throughput CALPHAD Development Method Designing Single Phase Alloy Platform For the Exploration of Light-Weighting Elements' as Passivators in Co-Free FCC Alloys
Author(s) Peter Connors, John Scully
On-Site Speaker (Planned) Peter Connors
Abstract Scope The emergence of compositionally-complex alloys (CCAs) as a new frontier of corrosion-resistant alloys has opened doors for advanced optimization of the usage of corrosion-resistant elements for promoting passivation of each phase and self-healing. However, researchers must contend with a design space with vast compositional and microstructural possibilities, and a literature base focused primarily on one-off alloy development. In this work, a methodology for the rapid (~1 alloy/second) discovery of alloy compositions possessing the desired phase stability using the CALPHAD approach is presented. This approach utilizes equilibrium information regarding a specific composition such as its solidus temperature to maximize the probability of discovering an alloy with a disordered matrix-(or single-)phase microstructure. Further, a set of alloys with common Co-free FCC elements (FexNiy)80Cr10(AlaSibTic)10 was designed using this tool to further explore and define the specific impacts of light weighting elements Al, Si, Ti have on corrosion performance in a single-phase microstructure.
Proceedings Inclusion? Planned:
Keywords High-Entropy Alloys, Environmental Effects, Other

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A High Throughput CALPHAD Development Method Designing Single Phase Alloy Platform For the Exploration of Light-Weighting Elements' as Passivators in Co-Free FCC Alloys
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C-2: Atomistic Exploration of Orientation-Dependent Tribological Properties of CrCoNiFe at Elevated Temperatures
C-3: Investigation of Electrochemical Behavior of Novel Liquid-Phase Reinforced Cu-Ga-In Ternary Alloys
C-4: Metallographic Follow-Up of the Oxidation Progress With Time of Cast Cantor Alloys at 1000°C
C-5: Oxidized Surfaces and Deteriorated Subsurfaces of HEAs and MC-Strengthened HEAs Oxidized at High Temperature in Presence of Water Vapor
Coincident Design and Processing of Alloy and “Coating” in Multiprincipal Element Alloys
Corrosion and Passivation of Multi-Principal Element Alloys in Aqueous Solutions
Cyclic Oxidation of NiCoCr Alloys in Air and Air-Steam Environments
Cyclic Oxidation of Oxide Dispersion Strengthened Multi-Principal Element Alloys
Design and Evaluation of Multicomponent Rare Earth Disilicate Environmental Barrier Coatings
Development of NiCoFeCrAl Based High Entropy Alloys for Hydrogen Fueled Turbine System
Development of Novel Light Refractory Compositionally Complex Alloys for High Energy Accelerator Windows
Discovery of Oxidation-Resistant Refractory Complex, Concentrated Alloys Through High-Throughput Calculations and Experiments
Exploring the Synergistic Benefits of Al and Ti Addition on Aqueous Passivation of Cr Containing Fe-Cr-Al-Ti Alloys
First-Principles Study of Oxide Formation and Stability in the Equiatomic CoCrFeNi High-Entropy Alloy
Hot Corrosion Behavior of Nickel-Based Superalloys in Molten Na2SO4-MgSO4 Salts
Hydrogen Interaction With Stacking Faults in CoCrNiW Alloy: Insights From In-Situ ECCI During Tensile Testing
Hydrogen Solution in a TiNbZr Medium-Entropy Alloy
Improvement of Complex Oxide Properties by Doping
Influence of the Presence of Ti or Ta on the Oxidation Behavior at 1200°C of Cast MPEAs Derived From an Equimolar CoNiFeCr Basis
Investigating the Synergistic Effects of Al on Aqueous Passivation of Cr Containing [FeCoNi]-CrxAly Compositionally Complex Alloys (CCAs)
Investigation of Corrosion Behavior of FeCoNiCuZn High Entropy Alloy in H2SO4, NaCl, and KOH Electrolyte Solution
Investigation of Protective Potential of Al & Cr in Intermediate Temperature Oxidation of MoNbTaW Thin Film
Optimizing Strength-Corrosion Properties in Sulphuric Acid Environment via Tailoring V-Cr Composition in Medium-Entropy VCrCoNi Alloys
Oxidation Behavior of High Entropy Materials
Oxidation Mechanisms and Kinetics of As-Cast Versus Homogenized Refractory-Based High Entropy Alloys
Phase Stability and Magnetic Thermodynamics in Rocksalt High-Entropy Oxides
Predicting Alloy Oxidation Resistance Using Physics Informed Machine Learning
Probing Irradiation Response in CrFeMnNi Compositionally Complex Alloys Using High-Throughput Methodology
Recent Updates on Corrosion Behaviors of High Entropy Alloys
Strategies for Improved Oxidation Resistance of Refractory Multiple Principal Element Alloys

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