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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium Advances and Discoveries in Non-equilibrium Driven Nanomaterials and Thin Films
Presentation Title Harnessing compositional complexity with non-equilibrium synthesis
Author(s) Zac Ward
On-Site Speaker (Planned) Zac Ward
Abstract Scope High entropy materials offer vast and unexplored compositional phase spaces not accessible in traditional binary and ternary systems. Stabilization of single crystals comprised of 5 or more elements in increasingly complex and reduced symmetry crystal structures is providing new opportunities for discovery of unexpected exotic behaviors. Recent examples have shown that these systems can possessing unique combinations of structural, thermal, and chemical robustness in combination with continuously controllable electronic, magnetic, and optical properties suitable to advanced computing and sensing architectures. The extraordinarily short quench times associated with laser ablation are perfectly suited to stabilizing these materials in ideal randomly mixed solid solutions. We will discuss our ongoing work using non-equilibrium pulsed laser deposition to synthesize perovskite, spinel, and Ruddlesden-Popper single crystal high entropy oxides. A range of observed functionalities will be described through fundamental many body effects driven by inherent frustrations in the underlying spin, charge, and lattice order parameters.
Proceedings Inclusion? Planned:
Keywords Thin Films and Interfaces, Magnetic Materials, Electronic Materials

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Aggregation Dynamics in Nanoceria Under Polymerization of Ce Ions
Atomic-scale identification and manipulation of NV centers in nanodiamond
Characterization of High Quality Epitaxially Grown Diamond Thin Films
Controlled Kirkendall Voiding in Al-Au and Cu-Au Thin Films by Adjusting Sputtering Parameters
Conversion of c-Si and a-Si to Q-Si phases by ion irradiation
Creation of Multi-Principal Element Alloy Nanoparticles via Nanosecond Laser-Induced Dewetting
Decoupling Irradiation-induced Heterogeneities in Two-dimensional Semiconductors through Atomic Scale Mapping of Optical Modes and Infrared Excitations
Design of oxide thin films towards memristive switching and neuromorphic computing
Discovery of novel Q-phases of materials and impact on technology
Electron Beam Holography and Characterization of Defects in Multilayered Semiconductor Thin Films
Emerging 2D Hybrid Organic-Inorganic Thin Films for Next-generation Optoelectronic Devices
Enthalpy-driven self-healing in thin metallic films on flexible substrates
Exploring equilibrium and non-equilibrium bi-metallic materials with unique magneto-optical properties
Exploring multi element nanoparticles for sustainable catalysts
Exsolution-self-assembly in entropy designed oxide thin films
From Oxide Epitaxy to Membranes: Opportunities and Challenges
Functional Trimethylsilane Plasma Nanocoatings for Surface Modification of Cardiovascular Stents and Silver Nanowires
Harnessing compositional complexity with non-equilibrium synthesis
High Entropy Approach to Synthesize Water-Soluble Ceramics for Forming Sacrificial Templates to Grow Self-Standing Membranes and Sensors
Hybrid Organic-Inorganic Thin Film Deposition by Resonant Infrared, Matrix-Assisted Pulsed Laser Evaporation
Hydrogen Induced Resistive Switching in Perovskite Nickelate Thin Films
Hyperdoping: doping TiO2 beyond thermodynamic limits using Flash sintering
Integration of BaTiO3 on Si: from ferroelectricity to giant electrostriction
Interfacial coupling at bismuthate-titanate heterointerfaces
Light Assisted Resistive Switching Behaviour of PLD Grown VO2/TiO2 Thin Films
Macro-equimolar high entropy spinel thin films by pulsed laser deposition
Manipulation of Metal Insulator and topotactic Transition by interface modification in PLD grown epitaxial strongly correlated oxides VO2/TiO2 and their applications in nanomechanical resonator
Mechanisms of defect formation in physical vapor deposited phase-separating alloy films: A phase field study
Next-Generation Interconnects: Ruthenium and Ruthenium Alloys for Improved EM Resistance and Low Resistivity
Ordered nanocrystals induced efficient phase transformation in atomically-thin 2D-MoS2: A new paradigm of hydrogen generation and molecular sensing
Perspective on Diamond for Quantum Applications (Invited)
Photophysics of Quantum Defects in Layered Materials
Process dependent work function of carbide forming refractory metals
Self-assembly of plasmonic networks via far-from-equilibrium chemical dealloying
Structural, Electronic, and Optical Properties of 2D Metal Chalcogenophosphates for Electronic and Optoelectronic Devices
Tensile-strained self-assembly for novel quantum and photonic nanomaterials
Thin Film Growth on Mica: Challenges, Opportunities, and Applications for Micatronics

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