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Meeting 2023 TMS Annual Meeting & Exhibition
Symposium High Temperature Electrochemistry V
Presentation Title Electrochemical Reduction of Nd2O3+Fe2O3 Mixed Oxide Precursors in Calcium Chloride Melt
Author(s) Kunal Mondal, Prabhat K Tripathy
On-Site Speaker (Planned) Kunal Mondal
Abstract Scope Alloys of transition metals and rare earth elements are widely used as magnet materials in many industries including the clean energy sector. Currently, these magnets are prepared by a mixing-cum-melting technique. Efforts are currently underway to develop innovative ways to cut down the overall manufacturing costs of these magnets. Two of these efforts include preparation of these magnets by an electrochemical technique directly from their mixed oxide precursors and recycling of spent magnets. In the present research, an attempt was made to fabricate the neodymium iron (NdFe) master alloy directly from the mixed oxide precursors (Nd2O3 and Fe2O3 respectively) by cathodic polarization of the sintered precursors in a pool of molten calcium chloride at a temperature of 800oC. The presentation will discuss detailed experimental approaches pertaining to the fabrication of the oxide precursors and their subsequent electrochemical polarization to the alloy phase.
Proceedings Inclusion? Planned:
Keywords High-Temperature Materials, Surface Modification and Coatings, Ceramics

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Revised High Temperature Synthesis of UCl3 via Reaction of U with FeCl2
Blind Identification and Quantification of Analytes in Molten LiCl-KCl Eutectic
Chloro-aluminate Species Distribution Correlation with Electrical Conductivity of 1-ethyl-3-methyl Imidazolium Chloride (EMIC)-Aluminum Chloride (AlCl3) System
Cyclic Voltammetry for Real-time Oxide Ion Concentration Measurements of a Molten CaCl2
Electrochemical Behavior of Bismuth in molten LiCl-KCl-CaCl2
Electrochemical Properties of Ca-Sb Metal Battery with a Molten Chloride Electrolyte
Electrochemical Reduction of Nd2O3+Fe2O3 Mixed Oxide Precursors in Calcium Chloride Melt
Evaluating the Effects of Mixed Cation Molten Salt Electrolytes within the Li-Sb-Sn Liquid Metal Battery System
Evaluating the Electrochemical Recovery of Gd Using a Reactive Liquid Bi Electrode
Formation of Carbon Layer on Ni and Mo Through Electrochemical Reduction of Carbonate Ions in Molten LiCl
Numerical Modelling and Phase Field Modelling of Silicon Electrodeposition for Solar Cells at High Temperatures using Molten Salts
On the Separation of Niobium and Tantalum Metals via Molten Sulfide Electrolysis
Optimisation of the Anodic and Cathodic Current Densities during Nd Electrowinning Process
Oxide Ion Ceramic Sensor in Molten CaCl2 for Real Time Monitoring of the Direct Oxide Reduction Process
Relative Performance of Platinum, Iridium, and Ruthenium as Oxygen-Evolving Anodes during the Electrolytic Reduction of Uranium Oxide in Molten LiCl-Li2O
Study of Potentiometry for Monitoring Activity of GdCl3 in Molten LiCl-KCl Salt
The Demonstration and Optimization of Thin-cell Electrochemical Measurements in Molten LiCl-KCl Eutectic
The Impact of Moisture on the Electrochemical Behavior of Molten Calcium Chloride
Thermodynamic Properties of Nd-Fe Alloys via EMF Measurements in Molten Salts

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