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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium Spectroscopic Methods and Analysis for Nuclear Energy Related Materials
Presentation Title Examination of U19Pu10Zr fluff structure by X-ray tomography and time-of-flight secondary ion mass spectrometry
Author(s) Jake Fay, Fidelma Di Lemma, Cameron Howard, William Chuirazzi, Luca Capriotti, Jie Lian
On-Site Speaker (Planned) Jake Fay
Abstract Scope During irradiation a highly porous structure forms at the top of metallic fuel pins. EPMA analysis of this region have indicated that fluff is primarily composed of fuel isotopes in the same ratio seen in bulk fuel. This causes fluff to potentially have an impact on reactor neutronics during normal operation and transients. Previous studies pairing radiograph data and operation data from EBR-II have shown that fluff increases with burnup and decreases with Pu content. This work expanded on this by portioning cube shaped lift-outs from a U19Pu10Zr fluff sample. These lift-outs were then analyzed by X-ray tomography, scanning electron microscopy (SEM), and by time-of-flight secondary ion mass spectrometry (SIMS). These analyses provided new data into the pore structure and isotopic composition of fluff which will be used to gain insight into the formation mechanisms of fluff.
Proceedings Inclusion? Planned:
Keywords Nuclear Materials, Characterization,

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Advanced synchrotron characterization techniques for fusion materials science
Atomic-scale structural analysis of metastable zirconia
Complementarity of Neutrons and Positrons in Assessing Material Damage for Nuclear Applications
Correlative Investigation of Hydride Phase Formation and Transformation in Zircaloy-4 Using In Operando XRD and Feature Relocation EBSD-SEM
Correlative multi-modal analysis of nuclear graphite deformation mechanisms
Examination of U19Pu10Zr fluff structure by X-ray tomography and time-of-flight secondary ion mass spectrometry
In-situ Synchrotron Diffraction Investigations of a Scalable, Non-equilibrium Processing Route of ODS Steels for Nuclear Power
In situ helium implantation and Rutherford backscattering analysis of helium retention in amorphous SiOC
Investigating nuclear materials via laser based and positron annihilation spectroscopy techniques to understand their performance
Investigation of Local Defects in Ln-doped UO2: Impact of Fabrication Condition and Lanthanide type
Nano-scale Orientation Mapping Using Electron Backscatter Diffraction
Nanostructural Characterization of Electron Beam Welded Reactor Pressure Vessel Steel via XANES and Nano-CT
Nuclear Materials Research at the Synchrotron
Observing radiation enhanced diffusion in model Fe-Cr alloys and their oxides using atom probe tomography
Quantification of total irradiation damage in nuclear graphite using Raman spectroscopy
Revealing the Crystal Chemistry and Dissolution Kinetics of Doped Uranium Dioxide Nuclear Fuel
Studying the use of x-ray line profile analysis in irradiated materials via atomistic simulations
Synchrotron Characterization of Uranium Boride Alloyed with Chromium Oxidation Behavior
The Surprising Beneficial Effect of Low-Dose Proton Radiation on Suppressing the Corrosion Reactivity of Thermally Oxidized Iron
The use of spatially resolved EELS spectroscopy to elucidate irradiation induced phase transformation in Fe2O3 and Cr2O3 irradiated with ions and its impact on irradiation induced-loop formation
ToF-SIMS Characterization of Irradiated U-Zr FCCI Region Using Spectra Clustering
Vapor analysis by combination spectroscopy in a novel optical cell
X-Ray Diffraction-Computed Tomography (XRD-CT) Facility at NSLS-II for Studying Materials for Nuclear Applications

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