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Meeting 2024 TMS Annual Meeting & Exhibition
Symposium Structure-Property Relationships of Bulk Metallic Glasses
Presentation Title Dependence of the Nanometer-scale Structural Heterogeneity of a Bulk Metallic Glass on Its Fictive Temperature
Author(s) Xinzhe Wang, Amit Datye, Shuhan Zhang, John Thornton, Jan Schroers, Udo D. Schwarz
On-Site Speaker (Planned) Udo D. Schwarz
Abstract Scope The ability to modify the atomic-scale structure of metallic glasses by processing allows to tailor their mechanical properties. To fully use this ability, it is important to understand local ordering and density fluctuations, both of which manifest as structural heterogeneity. Here, we aim at revealing heterogeneity on the nanometer scale in samples made from Pt57.5Cu14.7Ni5.3P22.5, with virtually atomically flat samples being produced by thermoplastic forming followed by an annealing procedure that sets their fictive temperatures Tf. Atomic force microscopy imaging revealed both topography as well as the sample’s stiffness, modulations of which reflect structural inhomogeneity. The results show that samples featuring Tf’s close to the material’s glass transition temperature Tg of 235 °C are more homogeneous than samples with Tf’s that are lower or higher, a trend that is markedly different from the one found for the absolute values of the average stiffness, which monotonically increases for lower Tf’s.
Proceedings Inclusion? Planned:
Keywords Characterization, Mechanical Properties,

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Evidence of Pre-crystallization Structures in a Metallic Glass
Experimental Assessment of Local Environments in Metallic Glasses by 4D-STEM
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From Metallic Liquids to Metallic Glasses: In-situ Insights from Ultrafast Synchrotron X-ray Diffraction
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Prediction, Synthesis, and Characterization of Refractory Metallic Glass Powders
Processing Dependent Elastic Heterogeneities in Bulk Metallic Glasses
Rejuvenation of Metallic Glass through Memory Effect
Role of Medium-range Order in Atomic Dynamics of Liquid and Glass
Shear-band Cavitation Determines the Shape of the Stress-strain Curve of Metallic Glasses
Size-effects in Deformation of Rejuvenated and Annealed Metallic Glass
Spatial Evolution of Structural Motif Populations in Metallic Glasses during Shear Deformation
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Stress-accelerated Relaxation and Energy Dissipation in Metallic Glasses Revealed by Its Fractal Energy Landscape
Structural Response of Amorphous Solids to Elastic Strains
Super Elastic Strain Limit in Metallic Glass Films
Synchrotron X-ray Study of the Extreme Rejuvenation of Bulk Metallic Glasses by Triaxial Compression
Tailoring Structure, Residual Stresses and Heterogeneity in Metallic Glasses
The L–G Phase Transition in Binary Cu–Zr Metallic Liquids
The Mechanical Heterogeneity of Metallic Glasses
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