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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium REWAS 2025: Sustainable End-of-Life Management and Recycling Solutions for Batteries, Wind Turbines, and Photovoltaics
Presentation Title Enhancing Graphite Flotation Efficiency in The Presence of PVDF Binder via Surface Modifications by Ultrasound and UV Irradiation
Author(s) Shamanta Shafique, Mostafa Khodakarami, Md Shariful Islam, Manoranjan Misra
On-Site Speaker (Planned) Shamanta Shafique
Abstract Scope Recycling spent Li-ion batteries (LIBs) has gained attention for its role in sustainability. LIBs are valuable sources of graphite, used in various applications. Froth flotation is a promising method to separate graphite from spent LIBs but faces challenges due to the adhesion of polyvinylidene fluoride (PVDF), which alters graphite's hydrophobic properties. This study investigates the impact of PVDF on the flotation behavior and surface chemistry of graphite, examining wettability, electrokinetic properties, dispersion behavior, and flotation reagent adsorption. Techniques such as SEM, TGA, FTIR spectroscopy, and surface charge analysis provide insights into PVDF-graphite interactions. UV irradiation and ultrasound are explored to enhance PVDF desorption from graphite, improving flotation efficiency. These methods are assessed for their effectiveness in improving flotation efficiency. The findings indicate that these techniques significantly enhance the flotation process, offering an effective strategy for optimizing graphite recycling from spent LIBs and contributing to sustainable resource recovery and waste management.
Proceedings Inclusion? Planned:
Keywords Recycling and Secondary Recovery, Environmental Effects, Extraction and Processing

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A preliminary study on the recycling of oxide-based solid-state electrolytes
A Separation-Free and Purification-Free Method for Direct Production of Lithium-Rich Solution from Industrial-Grade Lithium-Ion Battery Waste
Advancing Circular Economy: Copper Recovery from E-Waste at Aurubis' New US Facility
Assessing Circular Economy in Photovoltaics: Life Cycle Perspective of Material Recovery, Reuse, and Remanufacturing
Barriers and Opportunities for Recycling Wind Turbine Blades in the United States
Critical Metals Recovery Via Multistep Pyrolysis of Spent Li-Ion Battery
Cryogenic Milling: The Highly Efficient, Environment Friendly, and Cost-Effective Process for the Recycling of High Purity Graphite from End-of-Life Lithium-Ion Batteries
Decommissioning, Characterization and Proposed Recycling Route of a Used Na-ZnCl2 Battery Cell
End-of-Life Recycling of Lithium-Ion Batteries in India
Enhancing Graphite Flotation Efficiency in The Presence of PVDF Binder via Surface Modifications by Ultrasound and UV Irradiation
Evaluating the Use of Wind Blade Residue and Recycled Aggregate in Low-Strength Concrete
Formation and Stability of Hydrides during Hydrogenation of NdFeB Magnets
Leaching Studies of LiCoO2 Cathode Powder in Phosphoric Acid Medium
Lithium Extraction from Wastewater of Li-ion Battery Direct-Recycling via Electrodialysis
Opportunities and Challenges in Lithium-Ion Battery Recycling – Emphasis on Pretreatment and Pyrometallurgical Processing
Optimizing Early-Stage Lithium Recovery: Investigating Oxalic Acid Leaching of Black Mass from End-of-Life NMC 622 Batteries
Photovoltaic Waste Management – Technologies and Strategies to Recycle c-Si and CI(G)S PV Waste
Pilot-Scale Hydrometallurgical Recycling of NMC Blackmass
Re-use of Wind Turbine Blades as Pedestrian Bridges in Beaverbrook Park
Recycling of Lithium-Ion Batteries Cathode Material Using Supercritical Fluid Extraction
Recycling of Raw-Crushed Wind-Turbine Blade for Concrete Production: Mechanical and Durability Performance
Recycling of Solar Wafers through Acid Leaching and Vacuum Refining.
Reductive Leaching investigation of Li-NMC Cathode Material Related to Spent Battery Recycling
Reductive Leaching of Cathode Active Material from Li-ion Batteries and Recovery of Copper Reductant
Reviews and Perspectives: Selective Leaching—A Promising Approach for Recycling Lithium Iron Phosphate Batteries
Right-Sizing Mining Capacity to Enable Future Battery Recycling
Solubilities of lithium, nickel, and cobalt oxides in deep eutectic solvents
Solvo-metallurgical Process for the Extraction of Lithium from End-of-Life Electric Vehicle Lithium-Ion Batteries
Supply Risk Aware Alloy Discovery and Design
Sustainable route for Nd recycling from end-of-life NdFeB magnet using a deep eutectic solvent
Synergistic Processing of Mixed LFP-NMC Black Mass for Improved Recycling Operations
Upcycling Spent Battery Cathodes into Steel with Green Hydrogen

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