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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium Advances in Ceramic Materials and Processing
Presentation Title Refractory high entropy metal-borides (Hf, Ta, Nb, Zr, W)Bx – microstructure, crystal structure and phase evolution
Author(s) Sercan Cetinkaya, Edward G. Obbard, Kevin J. Laws, Patrick A. Burr, Jamie J. Kruzic, Vanessa K. Peterson
On-Site Speaker (Planned) Sercan Cetinkaya
Abstract Scope Borides are commonly used in the nuclear industry due to boron's unique atomic properties. For instance, WB2-x is a promising fusion reactor shielding material owing to tungsten’s non-toxicity and high atomic number, while B4C is used as a control rod material in commercial fission power plants. This study aims to investigate the thermodynamic phase stability and phase composition of both as-cast and annealed refractory high-entropy metal borides. The analysis employs energy dispersive spectroscopy (EDS), X-ray and neutron powder diffraction techniques. Specifically, two different high-entropy boride compounds, (HfTaZrNb)Bx and (HfTaZrNbW)Bx (x=2 and 3), were synthesized using an arc melter to study the tungsten’s effect on these compositions. Their microstructure, crystal structure, and phase evolution were examined after homogenisation at 1500°C|1d. The results provide insight into how the addition of tungsten influences the properties and stability of these high-entropy borides, which could have significant implications for their use in advanced nuclear applications.
Proceedings Inclusion? Planned:
Keywords Other, Characterization, Nuclear Materials

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