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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium Additive Manufacturing of Refractory Metallic Materials
Presentation Title Design and Development of a Reduced Cost, Hf-Free Nb-Based Alloy for Additive Manufacturing Guided by CALPHAD
Author(s) Andrew O'Connor, Fernando L. Reyes Tirado, Carly Romnes
On-Site Speaker (Planned) Andrew O'Connor
Abstract Scope Given the high-cost of C103 and limited used in nuclear applications due to Hf content an alternative alloy is investigated. Ta, W, and Mo were chosen as Hf replacements based upon literature, reduced cost compared to Hf, and minimal neutron absorption. Solid solution yield strength at elevated temperature, solidification cracking susceptibility (using Kou’s criterion), and mass density were predicted using Thermo-Calc®. Ductilizing additions of Ti and Zr were based on expert knowledge. Multi-objective optimization based on the CALPHAD results and a cost metric was used to identify the most compelling compositional spaces to explore in the Nb-Ta-W-Mo-Ti-Zr system. These compositions were arc melted, sectioned, homogenized and tested for hardness as a proxy for mechanical properties. This work has indicated a promising set of compositions for a reduced cost, Hf-free replacement alloy for C103. The most promising compositions were atomized via ultrasonic atomization and additive manufactures using laser powder bed fusion.
Proceedings Inclusion? Planned:
Keywords Computational Materials Science & Engineering, ICME, Additive Manufacturing

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Comparison of Niobium Alloys C103 and Nb521
A New Angle to View the Battle with Oxygen in Molybdenum (Mo) Laser Powder Bed Fusion (LPBF)
Additive Manufacturing and High-Temperature Mechanical Behavior of High-Performance Refractory Alloys
Additive Manufacturing Informed Tantalum Alloy Development
Alloy Design and Microstructure-Property Relationships for Non-Equiatomic Ti-Zr-Nb-Ta-V-Cr Alloys with Tensile Ductility Made By Laser Powder Bed Fusion
Atomistic and Phase Field Simulations of Rapid Solidification Towards Refractory High Entropy Alloys
Computational Design of Graded Refractory Metal Structures
Custom Refractory Alloy Synthesis and Processing
Dense and Crack-Free Pure Tungsten Manufactured by Electron Beam Powder Bed Fusion Using Chemically Reduced Powder
Design and Development of a Reduced Cost, Hf-Free Nb-Based Alloy for Additive Manufacturing Guided by CALPHAD
Design and Development of a Refractory Complex Concentrated Alloy for Additive Manufacturing of Advancing Space Propulsion Components
Development of Molybdenum Alloys for Use with Powder Blown Laser Direct Energy Deposition Additive Manufacturing
Direct Energy Deposition of Tungsten by High Repetition High Power Femtosecond Laser
Directed Energy Deposition of Vanadium for Interlayers in Laser Welding
Effects of Oxygen Concentration in Ductile to Brittle Transition Temperature (DBTT) of Niobium C103 Fabricated via Laser Direct Energy Deposition.
Elevated Temperature Mechanical Performance of Historical Niobium Alloys
Elevated Temperature Testing of LP – DED C103 Thin Wall Structures
Enhanced Development of Tungsten Alloy Plasma Facing Materials
Exploring Fabrication Pathways, Phase Evolution and Structure-Property Relationships in High Temperature Functionally Graded Material
Hafnium-Based Refractory High Entropy Alloy Structures Produced Via Additive Manufacturing for Extreme Temperature Applications
High-Throughput Refractory Alloy Design for Additive Manufacturing
High Temperature Mechanical Properties of Laser Powder Bed Fusion Processed Nb-Based C103 Alloy
Hot-fire Testing of C103 Nozzle Extensions
Impact of Ceramic Nanoparticle Additions on the Properties of Additive Manufactured Refractory Metals
Impact of Multi-Scale Microstructural Heterogeneities on the Mechanical Behavior of Additively Manufactured and Post-Processed Nb-Based C103 Alloy
Impact of Stochastic Scanning Strategies in Electron Beam Powder Bed Fusion of Tungsten Alloys
Joining Niobium Refractory Alloy with Titanium Alloy in Direct Energy Deposition Additive Manufacturing Process
Laser Assisted Additive Manufacturing of W and W-Re for Fusion Power Application: Material Response in Manufacturing Environment
Laser Powder Bed Fusion of C103 and Refractory-Based Alloys - Material Development Using Ultrasonic Atomization
Microstructural Evolution and Mechanical Properties of Additively Manufactured W-Ta Alloys
Microstructural Evolution in Laser Powder Bed Fusion Processed W and W-Re
Process-Structure-Property Relationships of Additively Manufactured Refractory Metals
Prototype Elements Manufactured from Molybdenum and Tungsten Modified with Rhenium Using LPBF Technology
Reactive Synthesis in Additive Manufacturing of an Ultrahigh-Temperature Mo-Si-B-Ti Alloy
Solid State Additive Manufacturing of Refractory Alloys Using Cold Spray Technology
Thermo-Mechanical Testing Approach of Additive Manufactured Ultra-High Temperature Refractory Alloys
Thermomechanical Model Based Approach to Mitigate Crack Susceptibility in Additive Manufactured Refractory Material.
Uncovering the Ultra-High Temperature Deformation Mechanisms of Novel Refractory Alloys
Understanding the Elevated Temperature Properties of Niobium-Based Alloys Relevant to Aerospace Applications
WC-Based Functionally Graded Materials Fabricated by Laser Powder Directed Energy Deposition

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