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Meeting MS&T24: Materials Science & Technology
Symposium 2024 Undergraduate Student Poster Contest
Presentation Title SPU-34: High-permittivity polysiloxane dielectrics obtained through polar group functionalization
Author(s) Hao Gu, Codrin Tugui, Mihai Duduta
On-Site Speaker (Planned) Hao Gu
Abstract Scope Dielectric elastomer actuators (DEAs) are an emerging field of soft transducer technology with potential applications as soft robotic actuators, generators, sensors, and capacitors. However, PDMS-based DEAs operate on high voltages due to PDMS’s low relative permittivity. We explore the functionalization of hydroxyl-terminated polydimethyl-vinylmethylsiloxane copolymers with polar thiol groups to tune viscoelastic and electrical properties. We find that the functionalized polymer showed an increase in relative permittivity and a decrease in Young’s Modulus compared to PDMS. Electrostatic modeling shows that a DEA made from this novel material would operate on a lower voltage compared to a PDMS-based DEA. In addition to low-voltage operation, the high-permittivity elastomer dielectrics developed in this work allow DEAs and capacitors to be significantly miniaturized, reducing material usage and decreasing electronic waste. Currently, we are working on applications of this improved elastomer in DEA-based non-electromagnetic rotary motors and flexible interdigitated capacitance sensors with high sensing resolution.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

SPU-10: Machine Learning Model Explainability for the Development of High-Entropy Alloys
SPU-11: Chromium as a Catalyst for Large Particle Silicon Nitride
SPU-12: Glass-Refractory Interactions with Industrial Scaleup of LionGlass
SPU-13: Hands-On Instruction of First-Year College Engineering Students to Introduce Concepts of Ceramic Engineering
SPU-14: High Throughput Texture Analysis of Quartz via Automated Polarized Reflective Light Microscopy
SPU-15: Improving Density and Toughness of Ceria-Based Oxygen Ion Conductors
SPU-16: Photochemical Properties of WO3-TiO2 Eutectic Composites
SPU-17: Tailoring Cation Solubility in Rock Salt High Entropy Oxides
SPU-18: The Egyptian Blues, Preview: Color-Phase Assemblage Relationships
SPU-19: Advancing Cu-Al-Mn-Ni Alloys for Cost-Effective Elastocaloric Cooling
SPU-1: 3D Printing of Fully Integrated Flexible Humidity Sensor for Long-Term Health Monitoring
SPU-20: Electrical Transport Properties in 3D-Printed Variably Uniform 2D-Networks
SPU-21: The Effects of Corrugated Groove Pressing on Heterogenous Microstructure and Mechanical Properties in Copper Plates
SPU-22: Design of Silicone Composites with Controlled Hardness
SPU-23: On the Sources of Discrepancies between EBSD, SEM, and Optical Grain Size Measurements
SPU-24: Can Titanium in Stainless Steel Diminish Corrosion Resistance?
SPU-25: FAIRification of Highly Accelerated Lifetime Testing of Multi-Layer Ceramic Capacitors
SPU-26: Lifetime Analysis of Unencapsulated Solar Cell Passivation Layers
SPU-27: Modeling the Force-Extension Response of Binary Copolymers With Molecular Dynamics Simulations
SPU-28: Epitaxial Growth of Highly Conductive α-Ga2O3 by Suboxide Molecular-Beam Epitaxy
SPU-29: Growth of Twisted Nanomaterials: Chiral Halide Perovskite and Zinc Oxide
SPU-2: Anomaly Detection via In Situ Monitored Additively Manufactured Tensile Bars
SPU-30: Investigating Thermophysical Properties of Uranium Nitride Nuclear Fuel
SPU-31: Design and Development of an Integrated Metal Oxide Semiconductor (MOS) and Infrared (IR) Spectroscopy Sensor (GatorSense) for Lunar Volatile Detection
SPU-32: Cellulose and Ionic Liquid Solutions Properties and Rheology
SPU-33: Cs+ Intercalation in WO3 Photoelectrodes Inhibits Catalyst Deactivation for the Oxygen-Evolution Reaction
SPU-34: High-permittivity polysiloxane dielectrics obtained through polar group functionalization
SPU-35: Solvent Effect of Solution-Processed Electron Transport Layer on Organic Photovoltaics Performance
SPU-36: Sustainable Geopolymer Concrete for Construction Applications
SPU-37: The Design of Alloys for the Circular Economy
SPU-3: Comparison of Substrate and Sintering Condition Impacts on Aerosol Jet Printed Traces
SPU-4: Conductive Ink Morphology Analysis for Aerosol Jet Printing
SPU-5: Leveraging Bayesian Optimization for Fine-Tuning of Aerosol Jet Printing Processing Parameters
SPU-6: LignoCrete: Carbon Negative Mortars for 3D Printing
SPU-7: Stability of Aerosol Jet Printing for Flexible Electronics
SPU-8: Tailoring Microstructure and Twin-Induced Work Hardening of a Laser Powder Bed Fusion Manufactured Haynes 188 Alloy
SPU-9: Exploration and Classification of Materials Using a Tactile Sensor and Artificial Intelligence

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