About this Abstract |
Meeting |
2025 TMS Annual Meeting & Exhibition
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Symposium
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Innovative Hydrometallurgical Technologies for Environmentally Benign Processing and Remediation: An EPD Symposium Honoring Fiona Doyle
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Presentation Title |
Extraction of Lithium from Brine by Electrodialysis |
Author(s) |
Amilton Barbosa Botelho Junior, Kristen Abels, William Tarpeh |
On-Site Speaker (Planned) |
Amilton Barbosa Botelho Junior |
Abstract Scope |
Lithium is regarded as a critical raw material globally due to the expanding electric vehicle market. To meet battery supply demands, alternative lithium sources are being explored, with salt-lake brines emerging as a significant option. Electrodialysis (ED) offers a promising solution, providing high selectivity and productivity with reduced chemical reagent use and energy consumption. This study aims to evaluate the effect of common ions on lithium separation using ED with three different commercial membranes. Experiments were conducted in a 4-chamber reactor with feed solutions of equimolar chloride salts. The synthetic brine was designed to simulate brines. Our comprehensive investigation of various membranes also provides insights into process integration. Results from the synthetic brine experiments indicated the selectivity order as K > Na > Li >> Mg > Ca, with the final solution showing a higher ratio of lithium to divalent ions: Li/Mg and Li/Ca ratios were 5 and 3.5, respectively. |
Proceedings Inclusion? |
Planned: |
Keywords |
Hydrometallurgy, Extraction and Processing, Electrometallurgy |