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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium Innovative Hydrometallurgical Technologies for Environmentally Benign Processing and Remediation: An EPD Symposium Honoring Fiona Doyle
Presentation Title Extraction of Lithium from Brine by Electrodialysis
Author(s) Amilton Barbosa Botelho Junior, Kristen Abels, William Tarpeh
On-Site Speaker (Planned) Amilton Barbosa Botelho Junior
Abstract Scope Lithium is regarded as a critical raw material globally due to the expanding electric vehicle market. To meet battery supply demands, alternative lithium sources are being explored, with salt-lake brines emerging as a significant option. Electrodialysis (ED) offers a promising solution, providing high selectivity and productivity with reduced chemical reagent use and energy consumption. This study aims to evaluate the effect of common ions on lithium separation using ED with three different commercial membranes. Experiments were conducted in a 4-chamber reactor with feed solutions of equimolar chloride salts. The synthetic brine was designed to simulate brines. Our comprehensive investigation of various membranes also provides insights into process integration. Results from the synthetic brine experiments indicated the selectivity order as K > Na > Li >> Mg > Ca, with the final solution showing a higher ratio of lithium to divalent ions: Li/Mg and Li/Ca ratios were 5 and 3.5, respectively.
Proceedings Inclusion? Planned:
Keywords Hydrometallurgy, Extraction and Processing, Electrometallurgy

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Dissolution behavior of vanadium and iron from their oxide compounds in D2EHPA and investigation of the stripping behavior
Effect of Applied Potential on the Electrodeposition of Ti-Al Alloys in AlCl3:BMIC Ionic Liquid Electrolyte
Evaluation of the Glycine-Citrate System for the Leaching of Lead and Zinc from Mining Tailings
Extraction of Lithium from Brine by Electrodialysis
Green Synthesis of Silica-Based Photocatalysts from River Sand for Toxic Dye Removal From Industrial Waste Water
Hydrometallurgical Treatment of Nickel Saprolite Ores Using the Atlas Materials Process for Sustainable Critical Material Supply
Investigation on the Interaction between Acidic Organophosphorous Extractants and Tri-n-octylamine (TOA) for the Extraction of Rare Earths in HCl System
Rare Earth Elements Recovery Using Thermo-Responsive Virus
Removal Studies of Mo(VI) Ions from Simulated Metallurgical Waste Liquid by MIL-100(Fe)
Structure and Electrical Conductivity of Urea-Choline Chloride Deep Eutectic Solvent
Supported Liquid Membranes for Separation of Critical Raw Metals
Sustainable Hydrometallurgical Processes for Hazardous Element Control and Li-Ion Cathode Material Synthesis and Recycling
Total recycling of valuable constituents in black mass of spent lithium-ion batteries (LIBs) via environmentally friendly methods

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