About this Abstract |
Meeting |
2025 TMS Annual Meeting & Exhibition
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Symposium
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Additive Manufacturing: Length-Scale Phenomena in Mechanical Response
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Presentation Title |
Analyzing Hydrogen Diffusivity and Its Impact on Mechanical Behavior in Additively Manufactured FCC Alloys Using Nanoindentation |
Author(s) |
Dong-Hyun Lee, Yun Hee An, Yakai Zhao, Ju Hyeok Lee, Hyun You Kim, You Sub Kim, Soo Yeol Lee |
On-Site Speaker (Planned) |
Dong-Hyun Lee |
Abstract Scope |
Hydrogen diffusivity significantly affects the susceptibility of metals and alloys to hydrogen embrittlement. This study introduces a novel method to estimate hydrogen diffusivity in FCC alloys using nanoindentation experiments. By considering the plastic zone size around the indentation, the relationship between hydrogen-induced hardness changes and depth from the sample surface was established for two typical FCC alloys—316L stainless steel (SS) and CoCrNi medium-entropy alloy (MEA)—subjected to hydrogen charging and subsequent room-temperature aging. Combining this with the estimation of the through-thickness hydrogen concentration distribution, hydrogen diffusivity values were successfully determined. It was revealed that CoCrNi MEA exhibited a hydrogen diffusivity approximately 0.68 times higher than SS316L. Additionally, hydrogen-induced softening upon long-term aging at room temperature was observed in CoCrNi but not in SS316L. The distinct hydrogen-related phenomena in CoCrNi MEA were elucidated using density functional theory calculations of hydrogen solution energy and vacancy formation energy. |
Proceedings Inclusion? |
Planned: |
Keywords |
Additive Manufacturing, Characterization, High-Entropy Alloys |