About this Abstract |
Meeting |
2021 TMS Annual Meeting & Exhibition
|
Symposium
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Recycling and Sustainability for Emerging Technologies and Strategic Materials
|
Presentation Title |
Conductivity of AlCl3-BMIC Ionic liquid Mixtures Containing TiCl4 at Different Temperatures and Molar Ratios |
Author(s) |
Khalid Nahian, Aninda Nafis Ahmed, Pravin S. Shinde, Ramana G. Reddy |
On-Site Speaker (Planned) |
Khalid Nahian |
Abstract Scope |
The conductivity of the mixture of 1-butyl-3-methylimidazolium chloride (BMIC) with aluminum chloride (AlCl3) and titanium chloride (TiCl4) are systematically investigated over a range of temperature (70 oC- 110 oC) using the electrochemical impedance spectroscopy (EIS) method. The molar ratios of the components are being changed to study the effect of molar ratio on the conductivity. The conductivity data are plotted against temperature to check whether it obeys the Arrhenius law. The activation energy and the density are calculated. The conductivity of the solution increases with increasing temperature for every composition. For molar ratio changing, conductivity increases with increasing the TiCl4 content up to a certain composition then starts to decrease for each temperature. At room temperature, density of the solution increases with increasing the TiCl4 content in the solution. |
Proceedings Inclusion? |
Planned: |
Keywords |
Electrometallurgy, Titanium, |