About this Abstract |
Meeting |
2020 TMS Annual Meeting & Exhibition
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Symposium
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Advanced Materials for Energy Conversion and Storage VI
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Presentation Title |
Long Cycle-life and High-rate Magnesium-ion Battery Anode Enabled By Self-healing Through Near-room-temperature Solid-liquid Phase Transition |
Author(s) |
Eric Detsi, Lin Wang |
On-Site Speaker (Planned) |
Eric Detsi |
Abstract Scope |
Recently magnesium-ion batteries have been the subject of intense research as an alternative to lithium. Progress toward practical magnesium-ion batteries has been impeded by the absence of suitable electrolytes that are compatible with magnesium metal used as the negative electrode. A promising way to circumvent this electrolyte issue is through the use of alloy-type anodes as the negative electrode instead of magnesium metal. In this talk, I will present a novel high-performance alloy-type magnesium-ion battery anode which we have developed, which can be reversibly (de)magnesiated at the C-rate of 3C over 1000 cycles with excellent capacity retention. This exceptional performance is to thanks to the self-healing property of the active electrode material, which undergo solid-to-liquid phase transition when the cell operate around 30-40oC. Operando X-ray scattering techniques were used to demonstrate this self-healing property in real-time during magnesiation and demagnesiation.
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Proceedings Inclusion? |
Planned: Supplemental Proceedings volume |