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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium Advances in Magnetism and Magnetic Materials
Presentation Title Magnetic High Entropy Oxide for Water Pollutant Degradation
Author(s) Sanjula Pradhan, Nand Kishore Prasad
On-Site Speaker (Planned) Sanjula Pradhan
Abstract Scope This study describes the synthesis of a novel equi-atomic high-entropy oxide, (Mn0.6Cr0.6Co0.6Al0.6Li0.6)O4, with a spinel structure using the sol-gel method followed by calcination at 700°C. Characterization via XRD and TEM confirmed the formation of nanocomposite structures with desired phase compositions. Magnetic properties were investigated through M vs. H loops at 300 K and 5 K, showing soft magnetic behavior with a coercivity (HC) of 38 Oe at 300 K, transitioning to hard magnetic behavior with HC of 2524 Oe at 5 K. XPS revealed diverse oxidation states among the constituent elements. Further explored the material's synergistic properties, such as DRS-UV and Mott-Schottky measurements, demonstrated the oxide's catalytic potential to degrade organic dyes via interactions with reactive oxygen species generated through Fenton-like reactions with H2O2, photon absorption, or photo-Fenton mechanism. This study highlights the multifaceted properties of high-entropy oxides, integrating magnetic behavior and catalytic activity in a single-phase structure.
Proceedings Inclusion? Planned:
Keywords Magnetic Materials, Characterization, Environmental Effects

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B-12: Magnetocaloric Effect for Gd(Mn,Fe,Co)Si Alloys
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B-14: Synthesis and Magnetic Evaluation of Carbonaceous Spinel Ferrite Nanocomposites
B-44: Thermodynamic Investigation of Rare-Earth Reduced Magnet Systems
B-9: A Study on the Improvement of Coercivity of Nd-Fe-B Permanent Magnets by GBDP of Ternary Alloy
Characterization of Crystallographic and Magnetic Domain Structures in Magnetic Alloys Using Complementary TEM Techniques
Combinatorial Synthesis and Characterization of New, Stable Mn-, W-, Hf-, and Nb-Based Ternary Nitrides
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Development and Crystallography of fcc-bcc and bcc-fcc Precipitation in Soft Magnetic HEAs
Discovering New Functional Magnetic Materials Through High-Throughput Methods
Effect of Dy Substitution at Nd Sites in Melt-Spun Nd-Fe-B Permanent Magnet Ribbons: A Magnetic System for Electric Vehicles
Effects of Interstitial Elements on the Ordered Structure of Fe-Ni Alloys
Enhanced Mass Sensitivity of Self-Biased Magnetoelastic Sensors by Annealing-Induced Nanocrystallization
Experiments in Pulsed Magnetic Fields: A Powerful Tool to Study Multicaloric Materials
Fabrication of Alnico Permanent Magnets with Optimized Microstructures via Magnetic-Field-Assisted Direct Energy Deposition
First-Order Ferromagnetic Transition in MnFe(P,Si) Single Crystals
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High-Throughput Design and Discovery of Novel Magnetic Nitrides
Influence of Applied Magnetic Field on the Nature of First-Order Phase Transformations in R2In Cryogenic Magnetocaloric Materials
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Influence of Synthetic and Washing Protocols on Phase Purity and Magnetic Properties of Nd2Fe14B Powders Prepared by Calciothermic Reduction
Influencing Phase Development in Ferromagnetic Materials: Theory versus Practice
Internal Defect Detection and Characterization of Sm-Co Sintered Magnets by Ultrasonic Testing and Related Magnetic Properties
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Iron Nitride Permanent Magnets
Linking Quantum Mechanical Features to Structural Phase-Transformation in Inorganic Solids
Magnetic and Mechanical Hardening of Nano-Lamellar Magnets Using a Thermo-Magnetic Field
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Magnetic High Entropy Oxide for Water Pollutant Degradation
Magnetic Iron Disilicide Nanostructures: Computational Studies
Magnetic Model Informed Design of Architected Permanent Magnets for Electric Machines
Magnetic Properties of Sm2Fe17N3 at Low Temperature
Magneto-Optics, Revisited
Magnetocaloric Properties of LaFe11.5Si1.5 Alloys with Cobalt and Nickel Substitutions
Microstructure-Property Relationship for Hot Deformed Fine-Grained NdFeB Magnet with High Magnetic Properties Through Two-Step Spark Plasma Sintering
New Fe-rich Ferromagnets Without Critical Elements
Powder Consolidation of Ce-Based Permanent Magnets
Processing and Magnetic Properties of Nd/PrFeB Ring Magnets Produced by Extrusion
Protecting Ultrafine Grained Dy-Free Nd-Fe-B Sintered Magnets with Varied Passivation Techniques
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Structural, Magnetic and Mechanical Characterization of Fe-Co-Ni-B-Ti Powder Medium-Entropy Alloys
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