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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium REWAS 2025: Sustainable End-of-Life Management and Recycling Solutions for Batteries, Wind Turbines, and Photovoltaics
Presentation Title Reductive Leaching of Cathode Active Material from Li-ion Batteries and Recovery of Copper Reductant
Author(s) Arundhati Jena, Sreeya Chidere, Chenna Rao Borra, Mehmet Ali Recai Onal, Shaikh Saida, Prakash Venkatesan
On-Site Speaker (Planned) Arundhati Jena
Abstract Scope Decarbonization of the transportation sector has led to an increase in the adoption of lithium-ion batteries or LIBs. Efficient recycling of Li-ion batteries is essential to conserve resources and address challenges related to sustainable extraction and supply of critical battery materials like Li, Ni, Mn, and Co. Hydrometallurgical processes often employ expensive reductants to dissolve transition metals with higher oxidation states in the cathode active mass. To address this issue, the current study proposes an alternative and cost-effective approach by utilizing copper extracted from the spent batteries as a reducing agent, replacing costly options like H2O2, glucose, and citric acid. The dissolved copper is subsequently recovered through electro-winning. The study investigates the effect of H2SO4 concentration, and Cu amount on the dissolution of cathode active material. During leaching, a dissolution rate of more than 98% can be achieved, and the dissolved copper can be completely recovered through electro-winning.
Proceedings Inclusion? Planned:
Keywords Recycling and Secondary Recovery, Hydrometallurgy, Electrometallurgy

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A preliminary study on the recycling of oxide-based solid-state electrolytes
A Separation-Free and Purification-Free Method for Direct Production of Lithium-Rich Solution from Industrial-Grade Lithium-Ion Battery Waste
Advancing Circular Economy: Copper Recovery from E-Waste at Aurubis' New US Facility
Assessing Circular Economy in Photovoltaics: Life Cycle Perspective of Material Recovery, Reuse, and Remanufacturing
Barriers and Opportunities for Recycling Wind Turbine Blades in the United States
Critical Metals Recovery Via Multistep Pyrolysis of Spent Li-Ion Battery
Cryogenic Milling: The Highly Efficient, Environment Friendly, and Cost-Effective Process for the Recycling of High Purity Graphite from End-of-Life Lithium-Ion Batteries
Decommissioning, Characterization and Proposed Recycling Route of a Used Na-ZnCl2 Battery Cell
End-of-Life Recycling of Lithium-Ion Batteries in India
Enhancing Graphite Flotation Efficiency in The Presence of PVDF Binder via Surface Modifications by Ultrasound and UV Irradiation
Evaluating the Use of Wind Blade Residue and Recycled Aggregate in Low-Strength Concrete
Formation and Stability of Hydrides during Hydrogenation of NdFeB Magnets
Leaching Studies of LiCoO2 Cathode Powder in Phosphoric Acid Medium
Lithium Extraction from Wastewater of Li-ion Battery Direct-Recycling via Electrodialysis
Opportunities and Challenges in Lithium-Ion Battery Recycling – Emphasis on Pretreatment and Pyrometallurgical Processing
Optimizing Early-Stage Lithium Recovery: Investigating Oxalic Acid Leaching of Black Mass from End-of-Life NMC 622 Batteries
Photovoltaic Waste Management – Technologies and Strategies to Recycle c-Si and CI(G)S PV Waste
Pilot-Scale Hydrometallurgical Recycling of NMC Blackmass
Re-use of Wind Turbine Blades as Pedestrian Bridges in Beaverbrook Park
Recycling of Lithium-Ion Batteries Cathode Material Using Supercritical Fluid Extraction
Recycling of Raw-Crushed Wind-Turbine Blade for Concrete Production: Mechanical and Durability Performance
Recycling of Solar Wafers through Acid Leaching and Vacuum Refining.
Reductive Leaching investigation of Li-NMC Cathode Material Related to Spent Battery Recycling
Reductive Leaching of Cathode Active Material from Li-ion Batteries and Recovery of Copper Reductant
Reviews and Perspectives: Selective Leaching—A Promising Approach for Recycling Lithium Iron Phosphate Batteries
Right-Sizing Mining Capacity to Enable Future Battery Recycling
Solubilities of lithium, nickel, and cobalt oxides in deep eutectic solvents
Solvo-metallurgical Process for the Extraction of Lithium from End-of-Life Electric Vehicle Lithium-Ion Batteries
Supply Risk Aware Alloy Discovery and Design
Sustainable route for Nd recycling from end-of-life NdFeB magnet using a deep eutectic solvent
Synergistic Processing of Mixed LFP-NMC Black Mass for Improved Recycling Operations
Upcycling Spent Battery Cathodes into Steel with Green Hydrogen

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